An electron shell, also known as a main energy level, is a group of atomic orbitals with the same value of the principal quantum number n. Electron shells are made up of one or more electron subshells, or sublevels, which have two or more orbitals with the same angular momentum quantum number l. Electron shells make up the electron configuration of an atom. It can be shown that the number of electrons that can reside in a shell is equal to .
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The shell corresponding to the highest value of principal quantum number in the atom. The valence electrons in this shell are on average farther from the nucleus than other electrons; they are often directly involved in chemical reaction.