The term sulfide (also spelled sulphide, see spelling) refers to several types of
chemical compounds containing
sulfur in its lowest
oxidation number of −2.Formally, "sulfide" is the di
anion, S2−, which exists in strongly
alkaline aqueous solutions formed from H2S or alkali metal salts such as Li2S, Na2S, and K2S. Sulfide is exceptionally basic and, with a pKa > 14, it does not exist in appreciable concentrations even in highly alkaline water, being undetectable at pH < ~15 (8 M
NaOH). Instead, sulfide combines with protons to form HS−, which is variously called hydrogen sulfide ion, hydrosulfide ion, sulfhydryl ion, or bisulfide ion. At still lower pH's (<7), HS− converts to H2S,
hydrogen sulfide. Thus, the exact sulfur species obtained upon dissolving sulfide salts depends on the pH of the final solution.
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