Title for graph should read "Indirect Bandgap" as opposed to DIRECT BANDGAPIn
semiconductor physics, an indirect bandgap is a
bandgap in which the minimum energy in the
conduction band is shifted by a
k-vector relative to the valence band. The k-vector difference represents a difference in
momentum.Semiconductors that have an indirect bandgap are inefficient at emitting
light. This is because any
electrons present in the conduction band quickly settle into the energy minimum of that band. Electrons in this minimum require some source of momentum allowing them to overcome the offset and fall into the
valence band.
Photons have very little momentum compared to this energy offset –. The momentum "kick" of a photon being emitted or absorbed is negligible and direct transitions are essentially 'vertical' in k-space.
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