Hydroformylation
Hydroformylation, also known as oxo synthesis, is an important industrial process for the production of aldehydes from alkenes. This chemical reaction entails the addition of a formyl group (CHO) group and a
hydrogen atom to a carbon-carbon double bond. This process has witnessed continuous growth since its invention in the 1930’s: production capacity reached 6.6×106 tons in 1995. It is important because the resulting aldehydes are easily converted into many secondary products. For example, in the
Shell higher olefin process (SHOP), the resulting aldehydes are hydrogenated to
alcohols, which are converted to
detergents. Hydroformylation is also used in specialty chemicals, relevant to the
organic synthesis of
fragrances and natural products. The development of hydroformylation, which originated within the German coal-based industry, is considered one of the premier achievements of 20th century industrial
chemistry.
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Oxo-syntes
Oxo-syntes är en kemisk reaktion där
olefiner (
alkaner) reagerar med
syntesgas över en
katalysator, bestående av metallerna
rodium eller
kobolt, som är i komplex med organiskt material, t.ex. trifenylfosfin.
Aldehyd fås som produkter. Syntesgasen måste vara extremt ren. Av eten + syntesgas fås propanal (propanaldehyd). Om istället propen används, fås 1-butanal och 2-butanal.
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hydroformylation
شيمى : هيدرو فرميل دار کردن
hydroformylation
hydroformylation
f.
醛化,烯烴醛化
hydroformylation
hydroformylation
f.
醛化,烯烃醛化