Aufbau principle
The Aufbau principle from German "Aufbau" meaning "construction" (also Aufbau rule or building-up principle), is used to determine the
electron configuration of an
atom,
molecule or
ion. The principle postulates a hypothetical process in which an atom is "built up" by progressively adding electrons. As they are added, they assume their most stable conditions (
electron orbitals) with respect to the nucleus and those electrons already there.
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aufbau principle (aufbau construction; building-up principle)
An approximate procedure for writing the
ground state electronic configuration of atoms. The configuration of an atom is obtained by inserting one electron into the configuration of the atom immediately to its left on the periodic table. The electron is inserted into the subshell indicated by the element's
period and
block .