Allotropy (Gr. allos, other, and tropos, manner) is a behavior exhibited by certain
chemical elements: these elements can exist in two or more different forms, known as allotropes of that element. In each different allotrope, the element's atoms are bonded together in a different manner. For example, the element
carbon has two common allotropes:
diamond, where the carbon atoms are bonded together in a
tetrahedral lattice arrangement, and
graphite, where the carbon atoms are bonded together in sheets of a hexagonal lattice. Note that allotropy refers only to different forms of an element within the same phase or
state of matter (i.e. different
solid,
liquid or
gas forms) - the changes of state between solid, liquid and gas in themselves are not considered allotropy. For some elements, allotropes have different molecular formulae which can persist in different phases - for example, the two allotropes of
oxygen (
dioxygen, O2 and
ozone, O3), can both exist in the solid, liquid and gaseous states. Conversely, some elements do not maintain distinct allotropes in different phases: for example
phosphorus has numerous solid allotropes, which all revert to the same P4 form when melted to the liquid state.
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