Vivianite Fe3(PO4)2·8(H2O), hydrated
iron phosphate, is a secondary
mineral found in a number of geological environments. Usually found as deep blue to deep bluish green prismatic to flattened crystals, most crystals rather small to microscopic, larger ones are rare.It is formed by the alteration of ore deposits near the surface, or of primary phosphates in
pegmatites. Vivianite crystals are often found inside
fossil shells, such as those of
bivalves and
gastropods, or attached to fossil bone.Vivianite darkens upon exposure to light, and was named in
1817 after J.G. Vivian, an
English mineralogist who first discovered crystals of the mineral in
Cornwall.
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General Information:

Chemical Formula:
Fe++3(PO4)2·8(H2O)

Composition:
(Molecular Weight = 501.61 gm)
Iron 33.40 %
FePhosphorus 12.35 %
P Hydrogen 3.22 %
H Oxygen 51.03 %
O 
Empirical Formula:
Fe3+3(PO4)2·8(H2O)

Environment:
Common secondary mineral in the gossan of metallic ore deposits, pegmatates, sedimentary authigenic mineralization in association with organic materials.

IMA Status:
IMA Approved

Name Origin:
Named after the English mineralogist, J. G. Vivian.
Physical Properties:

Cleavage:
[010] Perfect

Color:
colorless, green, blue, dark green, or dark bluish green.

Density:
2.6 - 2.7, Average = 2.65

Diaphaniety:
Transparent to translucent to opaque

Habits:
Divergent - Crystals radiate from a center without producing stellar forms., Concretionary - Rounded massive fine-grained materials., Earthy - Dull, clay-like texture with no visible crystalline affinities, (e.g. howlite).

Hardness:
1.5-2 - Talc-Gypsum

Luminescence:
None.

Luster:
Vitreous - Pearly

Streak:
bluish white
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