In
organic chemistry, syn and anti addition are different ways in which two substituents can be added to a
double bond or
triple bond. This article will use alkenes as examples. Syn addition is the addition of two
substituents to the same side (or face) of a
double bond or
triple bond, resulting in a decrease in
bond order but an increase in number of substituents. Generally the
substrate will be an
alkene or
alkyne. Anti addition is in direct contrast to syn addition. In anti addition, two substituents are added to opposite sides (or faces) of a double bond or triple bond, resulting in a decrease in bond order but an increase in number of substituents.
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